⑴ 1,3-二溴5,5-二甲基海因(簡稱:二溴海因)的MSDS哪裡有啊
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**** MATERIAL SAFETY DATA SHEET ****
1,3-Dibromo-5,5-dimethylhydantoin, 98%
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: 1,3-Dibromo-5,5-dimethylhydantoin, 98%
Catalog Numbers:
16954-0000, 16954-0250, 16954-5000
Synonyms:
DDH; 1,3-Dibromo-5,5-dimethyl-2,4-imidazolidinedione
Company Identification (Europe): Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Company Identification (USA): Acros Organics
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For information in Europe, call: 0032(0) 14575211
For emergencies in the US, call CHEMTREC: 800-424-9300
For emergencies in Europe, call: 0032(0) 14575299
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
| CAS# | Chemical Name | % | EINECS# |Haz Symbols| Risk Phrases |
|----------------|--------------------------------------|----------|-----------|-----------|---------------+
| 77-48-5 |1,3-Dibromo-5,5-dimethylhydantoin | 98% | 201-030-9 |||
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
Hazard Symbols: O C N
Risk Phrases: 22 34 8 50
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns. Contact with combustible
material may cause fire. Very toxic to aquatic organisms.Moisture
sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not ince vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with combustible materials
may cause a fire.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe st, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: cream
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 187 - 191 deg C(decom)
Autoignition Temperature: Not available.
Flash Point: 155 deg C ( 311.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >190 deg C
Solubility in water: 0.1% (25?C)
Specific Gravity/Density:
Molecular Formula: C5H6Br2N2O2
Molecular Weight: 285.91
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, combustible materials, exposure to
moist air or water.
Incompatibilities with Other Materials:
Strong recing agents, strong bases, strong oxidizing agents, strong
acids, alcohols.
Hazardous Decomposition Procts:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide,
bromine.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 77-48-5: MU0686000
LD50/LC50:
CAS# 77-48-5: Oral, rat: LD50 = 250 mg/kg.
Skin, rabbit: LD > 20 g/kg
Carcinogenicity:
1,3-Dibromo-5,5-dimethylhydantoin -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50: <1mg/l; 96h; .Daphnia: Daphnia: EC50:
<1mg/l; 48h; .
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.*
Hazard Class: 5.1
UN Number: 3085
Packing Group: II
IMO
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.
Hazard Class: 5.1
UN Number: 3085
Packing Group: II
RID/ADR
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.
Hazard Class: 5.1
UN Number: 3085
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C N
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
R 50 Very toxic to aquatic organisms.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 77-48-5: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 77-48-5 is listed on Canada's DSL List.
CAS# 77-48-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 77-48-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/25/1999 Revision #2 Date: 8/11/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
⑵ 5,5-二甲基海因的用途說明:
用於合成鹵代海因;用於生產海因環氧樹脂;作為水溶性5,5-二甲基海因甲醛樹脂及粘合劑的原料;用於合成1,3(β-羥乙基)-5,5-二甲基海因;用於合成N-氯化雜環殺菌劑;用於合成β-氨基醇,作為抗結核的靶向N-乙醯轉移酶抑制劑;用作肝炎C病毒NS3絲氨酸蛋白酶的第二代選擇性抑制劑;用於合成N-氯化乙內醯脲;用作不對稱氯化內酯化反應試劑
⑶ 1-羥甲基-5,5-二甲基海因的海關編碼是什麼
基本信息:
中文名稱
1-羥甲基-5,5-二甲基海因
中文別名
1-羥甲基-5,5-二甲基乙內醯脲;強力佳登;1-羥甲基海因;1-(羥甲基)-5,5-二甲基海因;1-(羥甲基)-5,5-二甲基乙內醯脲;MDM乙內醯脲;
英文名稱
1-Hydroxymethyl-5,5-dimethylhydantoin
英文別名
1-Methylol-5,5-dimethylhydantoin;1-(Hydroxymethyl)-5,5-dimethylhydantoin;5,5-DIMETHYL-1-HYDROXYMETHYLHYDANTOIN;1-(hydroxymethyl)-5,5-dimethylimidazolidine-2,4-dione;
CAS號
116-25-6
中國海關編碼(HS-code):29339900.90
概述:
2933990090.
其他僅含氮雜原子的雜環化合物.
增值稅率:17.0%.
退稅率:13.0%.
監管條件:無.
最惠國關稅:6.5%.
普通關稅:20.0%.
申報要素:
品名,
成分含量,
用途,
烏洛托品請註明外觀,
6-己內醯胺請註明外觀,
簽約日期.
Summary:
2933990090.
heterocyclic
compounds
with
nitrogen
hetero-atom(s)
only.
VAT:17.0%.
Tax
rebate
rate:13.0%.
.
MFN
tariff:6.5%.
General
tariff:20.0%.
其他各國海關編碼海關數據詳見:http://ke.molbase.cn/cidian/29219
⑷ 二甲基海因類環氧樹脂 用什麼催化劑
以5,5-二甲基海因和環氧氯丙烷為原料,NaOH為催化劑,合成了5,5-二甲基海因環氧樹脂。考察了環氧樹脂的合成條件及其主要影響因素,用傅里葉變換紅外光譜,核磁共振法表徵了樹脂的結構。結果表明,在5,5-二甲基海因與環氧氯丙烷摩爾比為1:8,NaOH為理論加入量,反應溫度為80℃,反應3h得到環氧值為0.1899mol/100g,黏度為1.9383mL/g,數均分子量為1053,聚合度為4.4的環氧樹脂。在常溫下,所得樹脂能溶於水和一般有機溶劑。
⑸ 1,3-二羥乙基-5,5-二甲基海因的歐盟海關編碼是什麼
基本信息:
中文名稱
1,3-二羥乙基-5,5-二甲基海因
中文別名
1,3-二羥乙基-5,5-二甲基-2,4-咪唑啉二酮;DEDM
海因;
英文名稱
1,3-Bis(2-hydroxyethyl)-5,5-dimethylhydantoin
英文別名
N,N'-dihydroxyethyl-5,5-dimethylhydantoin;DEDM
HYDANTOIN;
CAS號
26850-24-8
歐盟海關編碼(HS-code):29339980
概述(Summary):29339980.
Heterocyclic
compounds
with
nitrogen
hetero-atom(s)
only.
General
tariff:6.5%.
⑹ 1,3-二氯-5,5-二甲基海因的韓國海關編碼是什麼
基本信息:
中文名稱
1,3-二氯-5,5-二甲基海因
中文別名
1,3-二氯-5,5-二甲基乙內醯脲;二氯海因;二氯二甲基海因;
英文名稱
1,3-Dichloro-5,5-dimethylhydantoin
英文別名
1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione;1,3-Dichloro-5,5-dimethyl-2,4-imidazolidinedione
DCDMH;
CAS號
118-52-5
韓國海關編碼(HS-code):2933999000
概述(Summary):2933999000.
Heterocyclic
compounds
with
nitrogen
hetero-atom(s)
only.
General
tariff:6.5%.
⑺ 5,5-二甲基海因的基本信息
中文名稱:5,5-二甲基海因
CAS RN: 77-71-4
外 觀:白色晶體
含 量:≥99.5%
熔 點:174~176℃
水 份:≤0.5%
灰 份:≤0.2%
⑻ 1,3-二氯-5,5-二甲基海因的海關編碼是什麼
基本信息:
中文名稱
1,3-二氯-5,5-二甲基海因
中文別名
1,3-二氯-5,5-二甲基乙內醯脲;二氯海因;二氯二甲基海因;
英文名稱
1,3-Dichloro-5,5-dimethylhydantoin
英文別名
1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione;1,3-Dichloro-5,5-dimethyl-2,4-imidazolidinedione
DCDMH;
CAS號
118-52-5
中國海關編碼(HS-code):29339900.90
概述:
2933990090.
其他僅含氮雜原子的雜環化合物.
增值稅率:17.0%.
退稅率:13.0%.
監管條件:無.
最惠國關稅:6.5%.
普通關稅:20.0%.
申報要素:
品名,
成分含量,
用途,
烏洛托品請註明外觀,
6-己內醯胺請註明外觀,
簽約日期.
Summary:
2933990090.
heterocyclic
compounds
with
nitrogen
hetero-atom(s)
only.
VAT:17.0%.
Tax
rebate
rate:13.0%.
.
MFN
tariff:6.5%.
General
tariff:20.0%.
其他各國海關編碼海關數據詳見:http://ke.molbase.cn/cidian/29389