⑴ 1,3-二溴5,5-二甲基海因(简称:二溴海因)的MSDS哪里有啊
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**** MATERIAL SAFETY DATA SHEET ****
1,3-Dibromo-5,5-dimethylhydantoin, 98%
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: 1,3-Dibromo-5,5-dimethylhydantoin, 98%
Catalog Numbers:
16954-0000, 16954-0250, 16954-5000
Synonyms:
DDH; 1,3-Dibromo-5,5-dimethyl-2,4-imidazolidinedione
Company Identification (Europe): Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Company Identification (USA): Acros Organics
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For information in Europe, call: 0032(0) 14575211
For emergencies in the US, call CHEMTREC: 800-424-9300
For emergencies in Europe, call: 0032(0) 14575299
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
| CAS# | Chemical Name | % | EINECS# |Haz Symbols| Risk Phrases |
|----------------|--------------------------------------|----------|-----------|-----------|---------------+
| 77-48-5 |1,3-Dibromo-5,5-dimethylhydantoin | 98% | 201-030-9 |||
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
Hazard Symbols: O C N
Risk Phrases: 22 34 8 50
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns. Contact with combustible
material may cause fire. Very toxic to aquatic organisms.Moisture
sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not ince vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with combustible materials
may cause a fire.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe st, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: cream
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 187 - 191 deg C(decom)
Autoignition Temperature: Not available.
Flash Point: 155 deg C ( 311.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >190 deg C
Solubility in water: 0.1% (25?C)
Specific Gravity/Density:
Molecular Formula: C5H6Br2N2O2
Molecular Weight: 285.91
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, combustible materials, exposure to
moist air or water.
Incompatibilities with Other Materials:
Strong recing agents, strong bases, strong oxidizing agents, strong
acids, alcohols.
Hazardous Decomposition Procts:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide,
bromine.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 77-48-5: MU0686000
LD50/LC50:
CAS# 77-48-5: Oral, rat: LD50 = 250 mg/kg.
Skin, rabbit: LD > 20 g/kg
Carcinogenicity:
1,3-Dibromo-5,5-dimethylhydantoin -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50: <1mg/l; 96h; .Daphnia: Daphnia: EC50:
<1mg/l; 48h; .
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.*
Hazard Class: 5.1
UN Number: 3085
Packing Group: II
IMO
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.
Hazard Class: 5.1
UN Number: 3085
Packing Group: II
RID/ADR
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.
Hazard Class: 5.1
UN Number: 3085
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C N
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
R 50 Very toxic to aquatic organisms.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 77-48-5: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 77-48-5 is listed on Canada's DSL List.
CAS# 77-48-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 77-48-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/25/1999 Revision #2 Date: 8/11/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
⑵ 5,5-二甲基海因的用途说明:
用于合成卤代海因;用于生产海因环氧树脂;作为水溶性5,5-二甲基海因甲醛树脂及粘合剂的原料;用于合成1,3(β-羟乙基)-5,5-二甲基海因;用于合成N-氯化杂环杀菌剂;用于合成β-氨基醇,作为抗结核的靶向N-乙酰转移酶抑制剂;用作肝炎C病毒NS3丝氨酸蛋白酶的第二代选择性抑制剂;用于合成N-氯化乙内酰脲;用作不对称氯化内酯化反应试剂
⑶ 1-羟甲基-5,5-二甲基海因的海关编码是什么
基本信息:
中文名称
1-羟甲基-5,5-二甲基海因
中文别名
1-羟甲基-5,5-二甲基乙内酰脲;强力佳登;1-羟甲基海因;1-(羟甲基)-5,5-二甲基海因;1-(羟甲基)-5,5-二甲基乙内酰脲;MDM乙内酰脲;
英文名称
1-Hydroxymethyl-5,5-dimethylhydantoin
英文别名
1-Methylol-5,5-dimethylhydantoin;1-(Hydroxymethyl)-5,5-dimethylhydantoin;5,5-DIMETHYL-1-HYDROXYMETHYLHYDANTOIN;1-(hydroxymethyl)-5,5-dimethylimidazolidine-2,4-dione;
CAS号
116-25-6
中国海关编码(HS-code):29339900.90
概述:
2933990090.
其他仅含氮杂原子的杂环化合物.
增值税率:17.0%.
退税率:13.0%.
监管条件:无.
最惠国关税:6.5%.
普通关税:20.0%.
申报要素:
品名,
成分含量,
用途,
乌洛托品请注明外观,
6-己内酰胺请注明外观,
签约日期.
Summary:
2933990090.
heterocyclic
compounds
with
nitrogen
hetero-atom(s)
only.
VAT:17.0%.
Tax
rebate
rate:13.0%.
.
MFN
tariff:6.5%.
General
tariff:20.0%.
其他各国海关编码海关数据详见:http://ke.molbase.cn/cidian/29219
⑷ 二甲基海因类环氧树脂 用什么催化剂
以5,5-二甲基海因和环氧氯丙烷为原料,NaOH为催化剂,合成了5,5-二甲基海因环氧树脂。考察了环氧树脂的合成条件及其主要影响因素,用傅里叶变换红外光谱,核磁共振法表征了树脂的结构。结果表明,在5,5-二甲基海因与环氧氯丙烷摩尔比为1:8,NaOH为理论加入量,反应温度为80℃,反应3h得到环氧值为0.1899mol/100g,黏度为1.9383mL/g,数均分子量为1053,聚合度为4.4的环氧树脂。在常温下,所得树脂能溶于水和一般有机溶剂。
⑸ 1,3-二羟乙基-5,5-二甲基海因的欧盟海关编码是什么
基本信息:
中文名称
1,3-二羟乙基-5,5-二甲基海因
中文别名
1,3-二羟乙基-5,5-二甲基-2,4-咪唑啉二酮;DEDM
海因;
英文名称
1,3-Bis(2-hydroxyethyl)-5,5-dimethylhydantoin
英文别名
N,N'-dihydroxyethyl-5,5-dimethylhydantoin;DEDM
HYDANTOIN;
CAS号
26850-24-8
欧盟海关编码(HS-code):29339980
概述(Summary):29339980.
Heterocyclic
compounds
with
nitrogen
hetero-atom(s)
only.
General
tariff:6.5%.
⑹ 1,3-二氯-5,5-二甲基海因的韩国海关编码是什么
基本信息:
中文名称
1,3-二氯-5,5-二甲基海因
中文别名
1,3-二氯-5,5-二甲基乙内酰脲;二氯海因;二氯二甲基海因;
英文名称
1,3-Dichloro-5,5-dimethylhydantoin
英文别名
1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione;1,3-Dichloro-5,5-dimethyl-2,4-imidazolidinedione
DCDMH;
CAS号
118-52-5
韩国海关编码(HS-code):2933999000
概述(Summary):2933999000.
Heterocyclic
compounds
with
nitrogen
hetero-atom(s)
only.
General
tariff:6.5%.
⑺ 5,5-二甲基海因的基本信息
中文名称:5,5-二甲基海因
CAS RN: 77-71-4
外 观:白色晶体
含 量:≥99.5%
熔 点:174~176℃
水 份:≤0.5%
灰 份:≤0.2%
⑻ 1,3-二氯-5,5-二甲基海因的海关编码是什么
基本信息:
中文名称
1,3-二氯-5,5-二甲基海因
中文别名
1,3-二氯-5,5-二甲基乙内酰脲;二氯海因;二氯二甲基海因;
英文名称
1,3-Dichloro-5,5-dimethylhydantoin
英文别名
1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione;1,3-Dichloro-5,5-dimethyl-2,4-imidazolidinedione
DCDMH;
CAS号
118-52-5
中国海关编码(HS-code):29339900.90
概述:
2933990090.
其他仅含氮杂原子的杂环化合物.
增值税率:17.0%.
退税率:13.0%.
监管条件:无.
最惠国关税:6.5%.
普通关税:20.0%.
申报要素:
品名,
成分含量,
用途,
乌洛托品请注明外观,
6-己内酰胺请注明外观,
签约日期.
Summary:
2933990090.
heterocyclic
compounds
with
nitrogen
hetero-atom(s)
only.
VAT:17.0%.
Tax
rebate
rate:13.0%.
.
MFN
tariff:6.5%.
General
tariff:20.0%.
其他各国海关编码海关数据详见:http://ke.molbase.cn/cidian/29389